by Akira Tsubouchi,* Daisuke Muramatsu, Takeshi Takeda*
Let's coordinate: Copper(I)-catalyzed cross-coupling of alkenyl- and arylsilanes with primary alkyl iodides as well as allylic and benzylic halides as C(sp3)![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
X electrophilic coupling partners has been realized by intramolecular activation through alkoxide coordination. This alkylation tolerates a range of functional groups including a free hydroxy group. IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene.
X electrophilic coupling partners has been realized by intramolecular activation through alkoxide coordination. This alkylation tolerates a range of functional groups including a free hydroxy group. IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene.
Angewandte Chemie International Edition
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