by Xing-zhong Shu, Casi M. Schienebeck, Wangze Song,
Ilia A. Guzei, Weiping Tang*
Chiral bicycles: Enantioenriched
bicyclo[5.3.0]decatrienes were prepared from readily available chiral
3-acyloxy-1,4-enynes (ACEs) for the first time. In most cases, the chirality of
the ACEs could be transferred to the bicyclic products with high efficiency.
Inversion of the configuration was observed, thus confirming the predictions of
previous computational studies.
Angewandte Chemie International Edition
Article first published online: 21 OCT 2013
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